Ruthenium catalyzed selective hydrosilylation of aldehydes

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DC Field	Value	Language
dc.contributor.author	Chatterjee, Basujit	-
dc.contributor.author	Gunanathan, Chidambaram	-
dc.date.accessioned	2025-04-02T11:23:05Z	-
dc.date.available	2025-04-02T11:23:05Z	-
dc.date.issued	2013-12-03	-
dc.identifier.citation	Chatterjee, B., & Gunanathan, C. (2014). Ruthenium catalyzed selective hydrosilylation of aldehydes. Chemical Communications (Cambridge, England), 50(7), 888–890.	en_US
dc.identifier.uri	https://doi.org/10.1039/C3CC47593J	-
dc.identifier.uri	http://idr.niser.ac.in:8080/jspui/handle/123456789/1253	-
dc.description.abstract	A chemoselective hydrosilylation method for aldehydes is developed using a ruthenium catalyst [(Ru(p-cymene)Cl2)2] and triethylsilane; a mono hydride bridged dinuclear complex [{(η6-p-cymene)RuCl}2(μ-H-μ-Cl)] and a Ru(IV) mononuclear dihydride complex [(η6-p-cymene)Ru(H)2(SiEt3)2] are identified as potential intermediates in the reaction and the proposed catalytic cycle involves a 1,3-hydride migration.	en_US
dc.language.iso	en	en_US
dc.publisher	Chemical Communications	en_US
dc.title	Ruthenium catalyzed selective hydrosilylation of aldehydes	en_US
dc.type	Article	en_US
Appears in Collections:	Journal Papers

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