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http://idr.niser.ac.in:8080/jspui/handle/123456789/1253| Title: | Ruthenium catalyzed selective hydrosilylation of aldehydes |
| Authors: | Chatterjee, Basujit Gunanathan, Chidambaram |
| Issue Date: | 3-Dec-2013 |
| Publisher: | Chemical Communications |
| Citation: | Chatterjee, B., & Gunanathan, C. (2014). Ruthenium catalyzed selective hydrosilylation of aldehydes. Chemical Communications (Cambridge, England), 50(7), 888–890. |
| Abstract: | A chemoselective hydrosilylation method for aldehydes is developed using a ruthenium catalyst [(Ru(p-cymene)Cl2)2] and triethylsilane; a mono hydride bridged dinuclear complex [{(η6-p-cymene)RuCl}2(μ-H-μ-Cl)] and a Ru(IV) mononuclear dihydride complex [(η6-p-cymene)Ru(H)2(SiEt3)2] are identified as potential intermediates in the reaction and the proposed catalytic cycle involves a 1,3-hydride migration. |
| URI: | https://doi.org/10.1039/C3CC47593J http://idr.niser.ac.in:8080/jspui/handle/123456789/1253 |
| Appears in Collections: | Journal Papers |
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