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Title: | meso-Tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin: influence of polar protic and aprotic solvents in tautomeric existence, exchange and morphology |
Authors: | Thomas, Ajesh P. Adinarayana, B. Srinivasan, A. |
Issue Date: | 11-Jul-2013 |
Publisher: | RSC Advances |
Citation: | Thomas, A. P., Sreedevi, K. C. G., Adinarayana, B., Ramakrishnan, S., & Srinivasan, A. (2013). meso-Tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin: influence of polar protic and aprotic solvents in tautomeric existence, exchange and morphology. RSC Advances, 3(38), 16967. |
Abstract: | A hitherto unknown meso-tetrakis(3,5-dihydroxyphenyl)N-confused porphyrin (NCPH) was synthesized and characterized. The typical 3H and 2H tautomeric existence of the N-confused derivative was controlled exclusively by protic and aprotic solvents rather than the established polar and non-polar driving forces. An unprecedented morphological change controlled by two tautomeric forms of NCPH during aggregation was investigated. |
URI: | https://doi.org/10.1039/C3RA42289E http://idr.niser.ac.in:8080/jspui/handle/123456789/1072 |
Appears in Collections: | Journal Papers |
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